对一类相变体积分数计算公式的修正          下载免费PDF全文

王曙光  叶国扬  宁杰远  楼小挺  刘平江 《地球物理学报》2007,50(6):1794-1801

考虑了相变过程中生成相晶核的真实形状,对1956年Cahn给出的颗粒边界成核情况下成核长大型相变的相变体积分数计算公式进行了修正;当初始实验数据是成核率、长大率时,两种相变体积分数计算公式的计算结果差别很大. 当初始实验数据是相变体积分数随时间变化的实验点时,两种相变体积分数计算公式所给出的计算结果的差别主要由拟合误差所致. 无论从哪种实验数据开始计算,两种不同的计算模型给出的生成相的颗粒大小都存在很大区别,这将影响对俯冲带流变结构的认识.  相似文献   

Prospects of search for diamondiferous kimberlites in the northeastern Siberian Platform     

N.V. Sobolev  A.V. Sobolev  A.A. Tomilenko  D.V. Kuz’min  S.A. Grakhanov  V.G. Batanova  A.M. Logvinova  T.A. Bul’bak  S.I. Kostrovitskii  D.A. Yakovlev  E.N. Fedorova  G.F. Anastasenko  E.I. Nikolenko  A.V. Tolstov  V.N. Reutskii 《Russian Geology and Geophysics》2018,59(10):1365-1379

The objects of study are Triassic hypabyssal diamondiferous kimberlites with an age of 220-245 Ma, containing macrocrysts of unaltered olivine. The latter are close in the time of formation to the main stage of intrusion of the Siberian Trap Province (252 Ma), which lasted less than 1 Myr. A comparative high-precision analytical study of the Ti, Ca, Cr, and Al impurity patterns in about 1000 olivine macrocryst samples with a forsterite content Fo = (100Mg/(Mg + Fe)) of 78 to 93 has demonstrated the effect of traps on the lithospheric composition. A comprehensive comparative study of diamonds from northern placers and Triassic kimberlites, including determination of their carbon isotope composition, was performed. Chromatography-mass-spectroscopic analysis of submicron fluid inclusions in diamonds from northern placers and kimberlites has shown predominant hydrocarbons of a wide range of compositions and subordinate contents of N₂, H₂O, and CO₂. These findings, together with the results of previous studies of subcalcic Cr-pyropes and diamonds found in the Lower Carboniferous gritstones of the Kyutyungde graben, lead to the conclusion that the Toluopka kimberlite field is promising for Paleozoic kimberlites. The results of comprehensive studies of diamonds and indicator minerals and U/Pb isotope dating of numerous detrital zircon samples from the basal horizon of the Carnian Stage (Upper Triassic) of the Bulkur site in the lower reaches of the Lena River suggest the presence of diamondiferous kimberlites within the northeastern Siberian Platform. The age of the probable primary diamond sources in the study area can be evaluated by an integrated U/Pb isotope dating of zircons, perovskites, and rutiles from the developed diamond placers and the basal horizon of the Carnian Stage.  相似文献   

Extremely magnesian olivine in igneous rocks     

P.Yu. Plechov  V.D. Shcherbakov  N.A. Nekrylov 《Russian Geology and Geophysics》2018,59(12):1702-1717

Published data on extremely magnesian olivine (> 96 mol.% forsterite) in igneous rocks were generalized and compared with data of new high-precision electron probe microanalyses of olivine from oxidized lavas of the Tolbachik Volcano (Kamchatka), chromitites from the Ray-Iz deposit (Russia), alkaline ultrabasic lavas from San Venanzo volcanoes (Italy), and skarns from the Kuh-i-Lal deposit (Tajikistan). All the found olivines resulted from low-temperature processes, such as subsurface oxidation, interaction with carbonates, and subsolidus re-equilibration. Low-temperature formation of olivine is reflected in its structure (hematite lamellae and abundance of inclusions of ore minerals) and abnormal contents of minor components (Mn, Ni, and Ca). The Mg content of olivine increases under the influence of postmagmatic processes and can be manifested in different rocks. This gives grounds to refine the genesis of olivine of exotic composition (93-96 mol.% forsterite) in some kimberlites, komatiites, and peridotites.  相似文献   

东昆仑希望沟橄榄辉长岩的岩石成因：地球化学、锆石U-Pb年龄与Hf同位素制约          下载免费PDF全文

孔会磊  栗亚芝  李金超  贾群子  国显正  王宇  姚学钢 《中国地质》2021,48(1):173-188

东昆仑古特提斯域镁铁-超镁铁质岩石的研究极为薄弱,文章报道了青海东昆仑东段希望沟橄榄辉长岩的岩相学、锆石U-Pb年代学、岩石地球化学及锆石Hf同位素资料,以确定该岩体的形成时代、岩石成因及构造环境,为东昆仑晚古生代—早中生代构造岩浆演化提供新的约束。岩石地球化学研究表明,希望沟橄榄辉长岩具有低SiO2(40.91%~42.14%)、低TiO2(0.29%~0.39%)、高MgO(28.18%~30.66%)、贫碱(K2O+Na2O=1.09%~1.36%)的特征,属亚碱性系列岩石,m/f比值介于5.03~5.39,属于铁质超基性岩类。岩石微量元素总体上富集大离子亲石元素(Rb、Th、U、K)和Pb,相对亏损高场强元素(Nb、P、Ti),ΣREE为28.17×10^-6~30.95×10^-6,(La/Yb)N为3.77~4.98,显示轻稀土富集的特征,δEu=0.80~0.95,具有弱的Eu负异常。利用LA-ICP-MS锆石U-Pb定年技术,获得橄榄辉长岩加权平均年龄为(264.9±1.2)Ma(n=26,MSWD=0.71),属中二叠世。锆石176Hf/177Hf比值为0.282709~0.283152,对应的εHf(t)=3.7~19.3,锆石单阶段Hf模式年龄TDM为135~753 Ma,平均为414 Ma,大于锆石U-Pb年龄。研究认为,橄榄辉长岩的岩浆源区主要为亏损地幔,可能有早期流体交代的岩石圈地幔组分的加入,并经历了地壳物质的混染。结合东昆仑区域构造演化,认为希望沟橄榄辉长岩是阿尼玛卿古特提斯洋俯冲阶段的产物,说明古特提斯洋在中二叠世已北向俯冲。  相似文献   

徐州白露山含金刚石橄榄玄武岩地球化学特征及其岩浆演化特征          下载免费PDF全文

蔡逸涛  施建斌  周琦忠  徐敏成  张琪 《中国地质》2021,48(6):1850-1864

江苏徐州地区位于华北克拉通的东南部,其区内及周边广泛发育碱性超基性岩-基性岩,其中不乏含金刚石母岩,但是主要为金伯利岩。笔者在苏北寻找金刚石原生矿的过程中,在徐州白露山地区发现了含金刚石的橄榄玄武岩。本区橄榄玄武岩SiO₂含量为42.64%~51.13%,K₂O+Na₂O为2.57%~5.93%,Al₂O₃为10.48%~13.53%,MgO含量变化范围较大,为3.11%~19.34%。以主量元素做TAS图解可以看出本区基性岩的投影点基本都落于玄武岩范围,属于高钾钙碱性。微量元素特征显示白露山的样品靠近OIB和火山弧区域。富集端元明显偏高的Ba/Th比值暗示玄武岩中含有大陆下地壳物质。而白露山橄榄玄武岩元素地球化学特征及组成变化范围大并不是主要由地壳混染引起的,而是因为源区含有残留的再循环大陆下地壳。这些地球化学特征说明徐州白露山橄榄玄武岩与辽宁、山东地区金伯利岩具有一定的成因联系,为该区金刚石找矿提供了有利线索。  相似文献   

Intrusion and Crystallization of a Spinifex-Textured Komatiite Sill in Dundonald Township, Ontario     

ARNDT  NICHOLAS T.; LESHER  C. MICHAEL; HOULE  MICHEL G.; LEWIN  ERIC; LACAZE  YANNICK 《Journal of Petrology》2004,45(12):2555-2571

Although komatiite has been defined as an ultramafic volcanicrock characterized by spinifex texture, there is a growing recognitionthat similar textures can also form in high-level dykes andsills. Here, we report the results of a petrological and geochemicalinvestigation of a 5 m thick komatiite sill in Dundonald Township,Ontario, Canada. This unit forms part of a series of komatiitesand komatiitic basalts, some of which clearly intruded unconsolidatedsediments. The komatiite sill is differentiated into a spinifex-texturedupper part and an olivine cumulate lower part. Features characteristicof the upper sections of lava flows, such as volcanic brecciaand a thick glassy chilled margin, are absent and, instead,the upper margin of the sill is marked by a layer of relativelylarge (1–5 mm) solid, polyhedral olivine grains that gradesdownwards over a distance of only 2 cm into unusually large,centimetre-sized, skeletal hopper olivine grains. This is underlainby a 1 m thick zone of platy spinifex-textured olivine and coarse,complex, dendritic, spinifex-textured olivine. The texture ofthe olivine cumulate zone in the overlying unit is uniform rightdown to the contact and a lower chilled margin, present at thebase of all lava flows, is absent. The textures in the silland the overlying unit are interpreted to indicate that thesill intruded the olivine cumulate zone of the overlying unit.Thermal modelling suggests that soon after intrusion, a narrowinterval of the overlying cumulate partially melted and thatthe liquid in the upper part of the sill became undercooled.The range of olivine morphologies in the spinifex-textured partof the sill was controlled by nucleation and crystallizationof olivine in these variably undercooled liquids. KEY WORDS: komatiite; intrusion; spinifex texture; olivine  相似文献   

济南辉长岩岩浆演化过程:来自熔体包裹体的证据     

丁相礼  任钟元  郭锋  钱生平  张乐  黄小龙  陈林丽  张银慧  洪路兵  张艳  吴亚东 《大地构造与成矿学》2016,(1):174-190

本研究首次报道了早白垩世济南辉长岩中橄榄石斑晶捕获的熔体包裹体的研究结果。济南辉长岩中橄榄石的Fo(60.3~74.6),Mn(2500~3500μg/g),Ni(70~1349μg/g),Fe/Mn比值(61.2~83.5),与源区母岩为纯的橄榄岩形成的熔体结晶出的橄榄石性质不同,可能与源区存在辉石岩的贡献有关。橄榄石中熔体包裹体主量元素具有较大的变化范围。熔体包裹体成分的标准矿物计算(CIPW)表明,MgO10%的熔体包裹体为含有霞石和橄榄石标准矿物分子的硅不饱和熔体,Mg O10%时为含石英标准矿物分子的硅饱和熔体。橄榄石中包裹有辉石和斜长石,说明岩浆演化过程应该处于开放环境。熔体包裹体的(~208Pb/~206Pb)i和(~207Pb/~206Pb)i与MgO具有良好的负相关关系,与SiO_2具有良好的正相关关系,以及熔体包裹体具有较高的SiO_2特征表明岩浆演化过程中可能有下地壳长英质组分的加入。熔体包裹体的Pb同位素落在EMI附近并向EMII延伸,其源区可能有EMI和EMII的贡献,熔体包裹体的主量元素成分说明其源区母岩可能有橄榄岩和辉石岩的贡献。  相似文献   

Seismic Properties of Anita Bay Dunite: an Exploratory Study of the Influence of Water     

Aizawa  Yoshitaka; Barnhoorn  Auke; Faul  Ulrich H.; Fitz Gerald  John D.; Jackson  Ian; Kovacs  IstvAn 《Journal of Petrology》2008,49(4):841-855

As a pilot study of the role of water in the attenuation ofseismic waves in the Earth's upper mantle, we have performeda series of seismic-frequency torsional forced-oscillation experimentson a natural (Anita Bay) dunite containing accessory hydrousphases, at high temperatures to 1300°C and confining pressure(P_c) of 200 MPa, within a gas-medium high-pressure apparatus.Both oven-dried and pre-fired specimens wrapped in Ni–Fefoil within the (poorly) vented assembly were recovered essentiallydry after 50–100 h of annealing at 1300°C followedby slow staged cooling. The results for those specimens indicatebroadly similar absorption-band viscoelastic behaviour, butwith systematic differences in the frequency dependence of strain-energydissipation Q^–1, attributed to differences in the smallvolume fraction of silicate melt and its spatial distribution.In contrast, it has been demonstrated that a new assembly involvinga welded Pt capsule retains aqueous fluid during prolonged exposureto high temperatures—allowing the first high-temperaturetorsional forced-oscillation measurements under high aqueousfluid pore pressure P_f. At temperatures >1000°C, a markedreduction in shear modulus, without concomitant increase inQ^–1, is attributed to the widespread wetting of grainboundaries resulting from grain-scale hydrofracturing and themaintenance of conditions of low differential pressure P_d =P_c – P_f . Staged cooling from 1000°C is accompaniedby decreasing P_f and progressive restoration of significantlypositive differential pressure resulting in a microstructuralregime in which the fluid on grain boundaries is increasinglyrestricted to arrays of pores. The more pronounced viscoelasticbehaviour observed within this regime for the Pt-encapsulatedspecimen compared with the essentially dry specimens may reflectboth water-enhanced solid-state relaxation and the direct influenceof the fluid phase. The scenario of overpressurized fluids andhydrofracturing in the Pt-encapsulated dunite specimen may havesome relevance to the high Q^–1 and low-velocity zonesobserved in subduction-zone environments. The outcomes of thisexploratory study indicate that the presence of water can havea significant effect on the seismic wave attenuation in theupper mantle and provide the foundation for more detailed studieson the role of water. KEY WORDS: seismic wave attenuation; water; dunite; hydrous mineral; shear modulus; viscoelasticity; olivine; grain-scale hydrofracturing  相似文献   

Exsolutions of Diopside and Magnetite in Olivine from Mantle Dunite, Luobusa Ophiolite, Tibet, China   总被引：1，自引：0，他引：1  

REN Yufeng  CHEN Fangyuan  YANG Jingsui  GAO Yuanhong 《《地质学报》英文版》2008,82(2):377-384

The exsolutious of diopside and magnetite occur as intergrowth and orient within olivine from the mantle dunite, Luobusa ophiolite, Tibet. The dunite is very fresh with a mineral assemblage of olivine （〉95%） ＋ chromite （1%-4%） ＋ diopside （〈1%）. Two types of olivine are found in thin sections： one （Fo = 94） is coarse-grained, elongated with development of kink bands, wavy extinction and irregular margins; and the other （Fo = 96） is fine-grained and poly-angied. Some of the olivine grains contain minor Ca, Cr and Ni. Besides the exsolutions in olivine, three micron-size inclusions are also discovered. Analyzed through energy dispersive system （EDS） with unitary analytical method, the average compositions of the inclusions are： Na20, 3.12%-3.84%; MgO, 19.51%-23.79%; Al2O3, 9.33%-11.31%; SiO2, 44.89%-46.29%; CaO, 11.46%-12.90%; Cr2O3, 0.74%-2.29%; FeO, 4.26%- 5.27%, which is quite similar to those of amphibole. Diopside is anhedral f＇dling between olivines, or as micro-inclusions oriented in olivines. Chromite appears euhedral distributed between olivines, sometimes with apparent compositional zone. From core to rim of the chromite, Fe content increases and Cr decreases; and A! and Mg drop greatly on the rim. There is always incomplete magnetite zone around the chromite. Compared with the nodular chromite in the same section, the euhedral chromite has higher Fe3O4 and lower MgCr2O4 and MgAI2O4 end member contents, which means it formed under higher oxygen fugacity environment. With a geothermometer estimation, the equilibrium crystalline temperature is 820℃-960℃ for olivine and nodular chromite, 630℃-770℃ for olivine and euhedral chromite, and 350℃-550℃ for olivine and exsoluted magnetite, showing that the exsolutions occurred late at low temperature. Thus we propose that previously depleted mantle harzburgite reacted with the melt containing Na, Al and Ca, and produced an olivine solid solution added with Na^＋, Al^3＋, Ca^2＋, Fe^3＋, Cr^3＋. With temperature d  相似文献   

江南造山带西段新元古代超基性岩体年代学和岩石地球化学研究及其对源区的约束     

寇彩化  刘燕学  李廷栋  何万双  张恒  丁孝忠  陆济璞 《岩石矿物学杂志》2016,35(6):947-964

本文研究对象为江南造山带西段湘西通道地区长界橄榄辉石岩。长界橄榄辉石岩锆石LA ICP-MS U-Pb加权平均年龄为701±11 Ma。长界橄榄辉石岩主要由单斜辉石、橄榄石和少量斜长石以及少量钛铁氧化物组成,指示在岩浆形成过程中单斜辉石、橄榄石和少量斜长石为主要分离结晶相。全岩具有低SiO_2(44.01%~47.72%)、Al_2O_3(6.77%~9.10%)、TiO_2(0.49%~0.75%)和全碱(Na_2O+K_2O=0.07%~2.04%)含量,而高MgO(23.97%~30.70%)含量的特征,岩石属于亚碱性拉斑玄武岩系列。长界橄榄辉石岩稀土元素总量(∑REE)较低,为25.7×10-6~55.6×10~(-6),全岩稀土和微量元素标准化图解与洋岛玄武岩(OIB)相似,具有富集轻稀土元素[(La/Yb)N为3.36~6.48]和富集大离子亲石元素(LILE)的特点,同时还显示出"弧岩浆"的地球化学性质,明显的Nb-Ta负异常,较高的Th/Nb值(0.52~0.81)和较低的Nb/La值(0.25~0.44)以及低Nb(1.11×10~(-6)~3.91×10~(-6))的特征。长界橄榄辉石岩具有高初始(87Sr/86Sr)i值(0.707 206~0.708 561)和正的εNd(t)值(0.25~0.41)。微量元素模拟结果表明,长界橄榄辉石岩起源于尖晶石相,其源区为受来自俯冲消减板片脱水或熔融形成的流体或熔体的交代的软流圈地幔,是软流圈地幔上涌并发生低度部分熔融的产物(4%~7%)。结合区域地质特征,推测长界橄榄辉石岩的形成可能与700 Ma时期江南造山带西段裂谷作用导致软流圈物质上涌并发生熔融有关。  相似文献